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VOLUME 94 | ISSUE 6 | PAGE 494
Propagating vibrational excitations in molecular chains
V. A. Benderskii, E. I. Kats^{\triangle\square}
Institute of Problems of Chemical Physics RAS, 142432 Chernogolovka, Russia
^\triangleLaue-Langevin Institute, F-38042 Grenoble, France
^\squareL.D. Landau Institute for Theoretical Physics, RAS, Moscow, Russia

Abstract
We investigate quantum dynamics of vibrational excitations in one-dimensional (1D) molecular chain. Our model includes nearest neighbor interaction between identical molecular sites and one impurity atom placed in the middle (n=0). We show that upon exciting the impurity site, its excess energy for relatively long for molecular scales time up to 100 ps is not redistributed uniformly among all other degrees of freedom. On the contrary an excitation propagates along the chain, reflected from the chain ends, and quantum interference of these waves yields to recurrence cycles and echo phenomena. For a critical cycle number kc, echo components of the neighboring cycles start to overlap, and eventually for k \gg k_c dynamics looks like chaotic one. The critical cycle number kc depends on the coupling strength 0 \leq C \leq 1 of the impurity site with its neighbors n = \pm 1. kc achieves the maximum for C2 = 1/2. Our results are in qualitative agreement with experimental data on vibrational excitations in various (CH2)n molecular chains, and besides offer a way for loss-free energy transfer between separated in space reaction centers.


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